Empirical scheme of vinyl monomers relative
reactivity in radical addition reactions
Choose radical, reper monomer and a group of monomers to investigate.
Then submit quiery to get table of relative rate constants (calculated
and, when possible, experimental.
No warranty that constants in a series are of one and the same author.
Relative constants are calculated as a ratio of absolute constants from
[2]. Temperature: 50-60 C, constant in each series).
Author will appreciate any hints where he can get other (than
[2]) sources of experimental data on radical addition,
especially within Internet. Thanks.
E-mail: abc@polytech.yaroslavl.su